EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
<=0.3
EC/CAS
236-675-5/13463-67-7
Name of the chemical
Titanium dioxide
Concentration
2119457014-47
Revision date
2021-08-07
Product name
3M Scotch-Seal 560 Polyurethane Adhesive Sealant, Black, Grey or White
Icons in SDS
Company name
3m company
E-mail address of the competent person responsible for the Safety Data Sheet
tox.uk@mmm.com
Signal word
Danger
Hazard statements (CLP)
H317, H319, H334, H412
Code
Statements
H317
May cause an allergic skin reaction
H319
Causes serious eye irritation
H334
May cause allergy or asthma symptoms or breathing difficulties if inhaled
H412
Harmful to aquatic life with long lasting effects
Code
Statements
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P342+P311
IF experiencing respiratory symptoms: Call a POISON CENTER/doctor/...
Code
Statements
EUH204
Contains isocyanates. May produce an allergic reaction.
EUH212
Warning! Hazardous respirable dust may be formed when used. Do not breathe dust.
2.1 Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008 The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. The carcinogenicity classification for titanium dioxide is not applicable based on physical form (material is not a powder). Respiratory Sensitization, Category 1 - Resp. Sens. 1; H334 Skin Sensitization, Category 1A - Skin Sens. 1A; H317 Hazardous to the Aquatic Environment (Chronic), Category 3 - Aquatic Chronic 3; H412 For full text of H phrases, see Section 16.
2.2 Label elements
CLP REGULATION (EC) No 1272/2008
Hazard pictograms
GHS08 (Health Hazard) | Ingredients: Ingredient CAS Nbr EC No. % by Wt 4,4'-methylenediphenyl diisocyanate 101-68-8 202-966-0 <= 0.3 Reaction mass of Bis(1,2,2,6,6-pentamethyl-4- 915-687-0 0.01 - 0.11 piperidyl) sebacate and Methyl 1,2,2,6,6-pentamethyl- 4-piperidyl sebacate
Hazard statements
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects.
Prevention
P261B Avoid breathing dust. P280E Wear protective gloves. P261B Avoid breathing dust. P280E Wear protective gloves.
Response
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. <=125 ml Precautionary statements P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician.
Supplemental label elements
EUH204 Contains isocyanates. May produce an allergic reaction. EUH212 Warning! Hazardous respirable dust may be formed when used. Do not breathe dust. 2% of the mixture consists of components of unknown acute dermal toxicity.
Contains
2% of components with unknown hazards to the aquatic environment Information required per Regulation (EU) 2020/1149 as regards diisocyanates: As from 24 August 2023 adequate training is required before industrial or professional use. Notes on labelling H319 not applied based on test data.
2.3 Other hazards
Persons previously sensitised to isocyanates may develop a cross-sensitisation reaction to other isocyanates.