Bondo Rubberized Undercoating 0737

Company name

3m company

SECTION 2: Hazards identification

OSHA 3.1 EMERGENCY OVERVIEW Specific Physical Form: Aerosol Odor, Color, Grade: Thick black solution with a solvent odor. General Physical Form: Liquid Immediate health, physical, and environmental hazards: Extremely flammable liquid and vapor. Aerosol container contains flammable gas under pressure. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Closed containers exposed to heat from fire may build pressure and explode. May cause target organ effects. May cause genotoxic or mutagenic effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Contains a chemical or chemicals which can cause cancer.

Potential health effects

Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Inhalation: Intentional concentration and inhalation may be harmful or fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Prolonged or repeated exposure may cause: Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Genotoxicity and Mutagenicity: May interact with genetic material and possibly alter gene expression. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation ASPHALT 8052-42-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. Get immediate medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. 4.2 NOTE TO PHYSICIANS Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature >=470 ºF [Test Method: Estimated] Flash Point <=0 ºF [Test Method: Closed Cup] Flammable Limits(LEL) 1.6 % Flammable Limits(UEL) 6.5 % OSHA Flammability Classification: Class IB Flammable Liquid 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Closed containers exposed to heat from fire may build pressure and explode. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. 6.2. Environmental precautions Place in a metal container approved for transportation by appropriate authorities. Clean-up methods Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Seal the container. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. Do not pierce or burn container, even after use. No smoking while handling this material. Do not spray near flames or sources of ignition. Avoid breathing of vapors, mists or spray. Aerosol container contains flammable gas under pressure. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Do not breathe vapors. Avoid contact with oxidizing agents.

Storage

Store away from acids. Store away from heat. Store out of direct sunlight. Keep container tightly closed. Do not store containers on their sides. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Use in an enclosed process area is recommended. Use in a well-ventilated area. If exhaust ventilation is not available, use appropriate respiratory protection. Do not use in a confined area or areas with little or no air movement. Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Indirect Vented Goggles . 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Do not breathe vapors. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges . Select and use respiratory protection to prevent an inhalation exposure based on the results of an exposure assessment. Consult with your respirator manufacturer for selection of appropriate types of respirators. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information Alkanes, C1-4 ACGIH TWA 1000 ppm ASPHALT ACGIH TWA, as benzene 0.5 mg/m3 solubles, inhalable fraction CALCIUM CARBONATE CMRG TWA 10 mg/m3 CALCIUM CARBONATE CMRG STEL 20 mg/m3 Mineral Spirits CMRG TWA 100 ppm PROPANE OSHA TWA 1800 mg/m3 TOLUENE ACGIH TWA 20 ppm TOLUENE CMRG STEL 75 ppm Skin Notation* TOLUENE OSHA TWA 200 ppm TOLUENE OSHA CEIL 300 ppm * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)