HFE-71DE 3M(TM) Novec(TM) Engineered Fluid

Company name

3M

Signal word

Warning

SECTION 2: Hazards identification

3.1 EMERGENCY OVERVIEW Specific Physical Form: liquid Odor, Color; Grade: Clear, colorless liquid. Slight odor. General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause target organ effects.

Potential health effects

Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. !Page I of 9 42 MATERIAL SAFETY DATA SHEET HFE-71DE3M M Novec TM En ioeered Fluid IOnJn008 Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. lohalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. If thermal decomposition occurs: May be harmful if inhaled. May be absorbed following inhalation and cause targel organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause targel organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.

Environmental effects

AQUATIC TOXICITY: Testing results indicate that methyl nonafluoroisobutyl ether and methyl nonafluorobutyl ether have insignificant toxicity to aquatic organisms at their saturation point (Lowesl LC50, EC50, or IC50 > substance water solubility). 1,2-Trans-dichloroethylene is harmful to aquatic organisms (IO mg/L < Lowest LC50, EC50, or ICS0 < I 00 mg/L). These compounds are highly volatile and have high Henry's Law constants and are thus expected to move rapidly through vaporization from solution in an aquatic compartment or from a soil surface in a terrestrial compartment to the atmosphere. BIOCONCENTRA TJON: Methyl nonafluoroisobutylether, and methyl nonafluorobutylether are highly insoluble and very volatile. Bioconcentration is therefore unlikely and not expected as they are not likely to enter aqueous waste streams from typical uses and disposal, or, in the case ofa spill, remain in the aquatic or terrestrial compartments. The high potential for these components to move from aquatic or terrestrial environments to the atmosphere indicates bioconcentration is unlikely to occur as they are not expected to be bioavailable. Thus, emphasis has been placed on lhe atmospheric fate. 1,2-Trans-dichloroethylene has an octanol/water partition coefficient of<3 indicating it is unlikely to bioconcentrate. ATMOSPHERJC FATE: This product has Zero Ozone Depletion Potential (ODP). Page 2 of 9 43 MATERIAL SAFETY DATA SHEET HFE-71 OE 3M M Novec TM En ineered Fluid 10/23/2008 Atmospheric Lifetime: approximately 6 days for 1,2-trans-dichloroethylene and approximately 4.7 yr and 3.7 yr methyl for nonafluorobutyl ether and methyl nonafluoroisobutyl ether, respectively. Global Wanning Potential (GWP): 320 (JOO year 1TH, WMO 1998 method) for n-butyl and iso-butyl isomers and essentially zero for 1,2-trans-dichloroethylene. The mixture has a global warming potential of 160 on weight basis (100 year 1TH, WMO 1998 method). Atmospheric degradation products are expected to include for methyl nonafluoroisobutyl ether predominan1ly isoperfluorobutyric acid, CO2, HF, and perhaps also CF3COOH; for methyl nonafluorobutyl ether: n-perfluorobutyric acid, CO2, and HF.