JMTM Novec TM 1230 Fire Protection Fluid [FK-5-1-1 2]

Company name

3M

Signal word

Warning

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Specific Physical Form: Liquid Odor, Color, Grade: clear colorless, low odor. General Physical Form: Liquid Immediate health, physical, and environmental hazards:

Potential health effects

Eye Contact: . . . . . . Contact with the eyes during product use is not expected to result m s1g111ticant 1mtat1on. Pa~e I of 8 131 I MATERIAL SAFETY DATA SHEET JMTM Novec rn 1230 Fire Protection Flui<l !f'K-5-1-12! 01/21/11 Skin Contact: Contact with the skin during product use is not expected to result in significant irritation. Inhalation: lfthem1al decomposition occurs: May be hannful if inhaled. Ingestion: No health effects are expected.

Environmental effects

This substance has a high Henry's Law constant and therefore will be primarily found in the atmosphere where photolysis will be the dominant reaction pathway. The ultimate degradation products of the photolysis reaction are HF, CO2 and trifluoroacetic acid (TFA). This substance does not contribute to ozone depletion: it has an atmospheric lifetime of approximately 5 days and a Global Wanning Potential (GWP) of I ( IPCC 2001 Method). J SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: No need for first aid is anticipated. Skin Contact: No need for first aid is anticipated. Inhalation: If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist. get medical attention. If Swallowed: No need for first aid is anticipated. J SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature Not Applicable F'lash Point No flash point Flammable Limits(LEL) Nol Applicable Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Flammable Limits(UEL) Not Applicable 5.2 EXTINGUISHING MEDIA Page 2 of 8 132 J MATERIAL SAFETY DATA SHEET 3M' "' Novec n, 1230 Fire Protection Fluid jFK-5-1-12! 01121/11 Product is a fire-extinguishing agent 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full proteclive equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Not applicable. Note: Sec STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to bum or explode. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a metal container approved for transportation by appropriale authorities. Dispose of collected material as soon as possible. Clean-up methods Observe precautions from other sections. Call 3M- HELPS line ( 1-800-364-3577) for more information on handling and managing the spill. Contain spill. Working from around lhe edges of the spill inward, cover with bentoni1e, vern1iculite, or commercially available inorganic absorbent material. Mix in sufficienl absorbent until it appears dry. Collect as much ofthc spilled material as possible. Clean up residue. Seal the comainer. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal re ulalions. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING For industrial or professional use only. Contellls may be under pressure, open carefully. Do not breathe thermal decomposition products.

Storage

Keep container in well-ventila1ed area. Store 0111 of direct sunlight. Store away from heal. Store away from strong bases, amines, and alcohols. j SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Provide appropriate local exhaust ventilation on open containers. For those situations where the fluid might be exposed to extreme overheating due to misuse or equipment failure, use with appropriate local exhaust ventilation sufficient to maintain levels of thermal decomposition products below their exposure guidelines. Page 3 of 8 133 I MATERIAL SAFETY DATA SHEET 3MT"1 Novcc TM 1230 Fire Protection Fluid lfK-5-1-12! Ol/21111 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2. l Eye/Face Protection Not applicable. 8.2.2 Skin Protection Not applicable. Gloves are not required. 8.2.3 Respiratory Protection As a good industrial hygiene practice: Avoid breathing of vapors, mists or spray. Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. If thermal decomposition occurs: Do not breathe vapors. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with

Additional information

I. I, 1.2.2,4.5.5.5-Nonalluoro-4- 3M TWA 150 ppm ( 1rilluoromc1hyl)-3-pcn ta none SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline Listed materials to avoid should not be mixed with liquid Novec 1230 fluid. Avoid direct sunlight and ultraviolet light. Hazardous Polymerization: Hazardous polymerization will not occur. Ha1..ardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion I lydrogen Fluoride During Combustion Hazardous Decomposition: Hydrogen fluoride has an ACGIH Threshold Limit Value of3 parts per million (as fluoride) as a Ceiling Limit and an The components of this product are in compliance with the chemical notification requirements of the National Industrial Chemical Notification and Assessment Scheme (NICNAS) of Australia, the Canadian Environmental Protection Act (CEPA) and the Ministry of Economy, Trade and Industry of Japan. This product is notilied in the Philippines as PMPIN-2005- 3. INTERNATIONAL REGULA TIO NS Contact 3M for more information. U.S. EPA. Signilicant New Alternatives Policy Program (SNAP) approved for uses is streaming and flooding fire protection application. I This MSDS has been prepared to meet the U.S.

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its com onenls. Page 5 of 8 135 j MATERIAL SAFETY DATA SHEET JMT" Novec T'1 1230 Fire Protection Fluid !FK-5-1-12! 01/21/ll Not determined. Please refer to existing literature on TFA CHEMICAL FATE INFORMATION Not determined. Photolytic half-life: 3-5 days. Photolytic degradation products may include Trifluoroacetic acid (TFA) NOTE: Hydrolysis is not expected to be a significant degradation pathway. Product is highly insoluble in water and volatile, and use as a clean extinguishing agent would not typically result in releases to aquatic environments. I SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in an industrial or commercial facility in the presence of a combustible material. Combustion products will include HF. Facility must be capable of handling halogenated materials. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. Reclaim if feasible. For information on product return, contact your distributor. EPA Hazardous Waste Number (RCRA): Not regulated I Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 98-0212-3031-7, 98-0212-3201-6, 98-0212-3203-2, 98-0212-3217-2, 98-0212-337 1-7, 98-0212-3414-5, 98-0212-3588-6 I For Transport Information, please visit http://3M.comrrransportinfo or call t-800-364-3577 or 651-737-6501. I SECTION 15: REGULATORY INFORMATION US FEDERAL REGULA TIO NS Contact 3M for more information. 31 l/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard -No Immediate Hazard - No Delayed Hazard - No STATE REGULATIONS Contact 3M for more information. Page 6 of 8 136 ! MATERIAL SAFETY DATA SHEET 3M'"' Novec TM 1230 Fire Protection Fluid jFK-5-l-l2j 01/21111 CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements ofTSCA. All the components of this product are listed on China's Inventory of Chemical Substances. The components of this material are in compliance with the new chemical nolification requirements for the Korean Existing Chemicals Inventory. Contact 3M for more information.

Further information

NJil>A Hazard Classification Health 3 Flammability O Reactivity I Special None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term. acute exposure to a material under conditions of fire, spill, or similar emergencies. Ha?.ard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known 10 be generated in significant quantities.

HMIS® ratings

Bealth O Flammability 0 Reactivity I Protection X - See PPE section I lazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical ha?.ards in the workplace. These Page 7 of 8 137 i MATERIAL SAFETY DATA SHEET 3MT" Novccn• 1230 Fire Protection Fluid IFK-5-1-12! 01/21111 ratings are based on the inherent properties of the material under expected conditions of normal use and an: not intended for use in emergency situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and Coatings Association (NPCA). Revision Changes: Section 1: Product use information was modified. Copyright was modified. Section 15: Inventories information was modified. Section 9: Boiling point infom,ation was modified. Section 5: Flammable limits (UE) information was modified. Section 5: Flammable lin1its (LEL) information was modified. Section 5: Flash point information was modified. Section 9: Flash point information was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Flammable limits (UEL) information was modified. Section 2: Ingredient table was modified. Section 8: Exposure guidelines ingredient information was modified. Section 6: 6.2. Environmental precautions heading was modified. Section 6: 6.1. Personal precautions, protective equipment and emergency procedt1res heading was modified. Section 14: ID Number Heading Template I was added. Section 14: ID Number(s) Template I was added. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPUED, INCLUDING, BUT NOT LIMITED TO, ANY fMPUED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to d,:termine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic trnnsfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the· MSDS available directly from 3M. 3M MSDSs are available al www.3M.com Page 8 of 8 138 IG-55 139 fike· ___________ M_A_TE_R_IA_L_s_AF_E_TY_ D_A~T~A~S~HE=--:.. 8 PRODUCT: IG-55 Version: 1.0 Date: March 26, 2007 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY Product Name IG-55 Chemical Formula N2 / Ar Company Identification Local filling station Emergency Phone Numbers Local filling station