2,4-D Ethyl ester

company name

AccuStandard, Inc

e-mail address of the competent person responsible for the Safety Data Sheet

edocs@accustandard.com

Signal word

Danger

Hazard statements(CLP)

H302, H315, H317, H318, H319

Code

Statements

H302

Harmful if swallowed

H315

Causes skin irritation

H317

May cause an allergic skin reaction

H318

Causes serious eye damage

H319

Causes serious eye irritation

Code

Statements

P202

Do not handle until all safety precautions have been read and understood.

P235

Keep cool.

P260

Do not breathe dust/fume/gas/mist/vapors/spray.

P262

Do not get in eyes, on skin, or on clothing.

P264

Wash ... thoroughly after handling.

P280

Wear protective gloves/protective clothing/eye protection/face protection.

P284

[In case of inadequate ventilation] Wear respiratory protection.

P338

Remove contact lenses, if present and easy to do. Continue rinsing.

P360

Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.

P404

Store in a closed container.

2.2 Label elements

0 2 HEALTH 2 0 FLAMMABILITY 0 - continued P264 - Wash thoroughly after handling. Do not take internally. Eye wash and safety equipment should be readily available. P280 - Protective gloves must be worn to prevent skin contact. P284 - Respiratory Protection: If workplace exposure limit(s) of product or any component is exceeded (see TLV/PEL), a NIOSH/MSHA approved air supplied respirator is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH/MSHA respirators (negative pressure type) under specified conditions (see your safety equipment supplier). Engineering and/or administrative controls should be implemented to reduce exposure. P338 - Eye contact: Immediately flush with plenty of water. After initial flushing, remove and contact lenses and continue flushing for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. P360 - Skin contact: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if symptoms occur. Wash clothing before reuse. P404 - Store in a tightly closed container.

Signal word

Danger

Hazard statements

H302 - Harmful if swallowed. (Acute toxicity, oral, category 4) H315 - Irritating to skin. (Skin corrosion/irritation, category 2) H317 - May cause allergic skin reaction. (Sensitization, skin, category 1) H318 - Risk of serious damage to eyes. (Eye damage/irritation, category 1) H319 - Causes severe eye irritation. (Eye damage/irritation, category 2A) Precautionary Codes: P202 - This product should only by used by persons trained in the safe handling of hazardous chemicals. P235 - Store in a cool dry place. P260 - Do not breathe dust. P262 - Do not get in eyes, on skin or clothing. - continued

2.3 Other hazards

2.2.1 - Symptom of Exposure Health/Environment Risk of serious damage to eyes. (Eye damage/irritation, category 1) May cause allergic skin reaction. (Sensitization, skin, category 1)

Potential health effects

Causes severe eye irritation. (Eye damage/irritation, category 2A) Irritating to mucous membrane and upper respiratory system. (Specific target organ toxicity, single exposure; Respiratory tract irritation, category 3) Harmful if swallowed. (Acute toxicity, oral, category 4) May be harmful if absorbed through the skin. (Acute toxicity, dermal, category 5) May be harmful if inhaled. (Acute toxicity, inhalation, category 5) Irritating to skin. (Skin corrosion/irritation, category 2) 2.2.3 - Routes of Entry Inhalation, ingestion or skin contact. 2.2.4 - Carcinogenicity This product is or contains a component that is not listed (ACGIH, IARC, NTP, OSHA) as a cancer causing agent.