3,3"-Dimethylbenzidine in Dichloromethane
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H302, H315, H332, H335, H350
Harmful if swallowed
Causes skin irritation
Harmful if inhaled
May cause respiratory irritation
May cause cancer
Do not handle until all safety precautions have been read and understood.
Keep container tightly closed.
Do not get in eyes, on skin, or on clothing.
Wash ... thoroughly after handling.
Wear protective gloves/protective clothing/eye protection/face protection.
[In case of inadequate ventilation] Wear respiratory protection.
Do NOT induce vomiting.
Remove contact lenses, if present and easy to do. Continue rinsing.
Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
Store in a closed container.
2.2 Label elements
1 * 2 HEALTH 2 0 1 FLAMMABILITY - continued P233 - Store in a tightly closed container. (P404) P262 - Do not get in eyes, on skin or clothing. P264 - Wash thoroughly after handling. Do not take internally. Eye wash and safety equipment should be readily available. P280 - Protective gloves must be worn to prevent skin contact. P284 - Respiratory Protection: If workplace exposure limit(s) of product or any component is exceeded (see TLV/PEL), or a risk assessment shows air-purifying respirators are appropriate, use of a NIOSH/MSHA approved air supplied respirator is advised. Use a full-face respirator with multi-purpose combination (US) or type ABEK (EN14387) respirator cartridges in absence of proper environmental control. Always use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Engineering and/or administrative controls should be implemented to reduce exposure. P331 - Ingestion: Do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. P338 - Eye contact: Immediately flush with plenty of water. After initial flushing, remove and contact lenses and continue flushing for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. P360 - Skin contact: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if symptoms occur. Wash clothing before reuse.
H302 - Harmful if swallowed. (Acute toxicity, oral, category 4) H315 - Irritating to skin. (Skin corrosion/irritation, category 2) H332 - Harmful if inhaled. (Acute toxicity, inhalation, category 4) H335 - May be irritating to mucous membrane and upper respiratory system. (Specific target organ toxicity, single exposure; Respiratory tract irritation, category 3) H350 - California Proposition 65 Warning: This product contains a component (or components) that may cause cancer in a concentration greater than or equal to 0.1%. H350 - This product is or contains a component that is classified (ACGIH, IARC, NTP, OSHA) as a possible cancer hazard. (Carcinogenicity, category 1B) Precautionary Codes: P202 - This product should only by used by persons trained in the safe handling of hazardous chemicals. - continued
2.3 Other hazards
2.2.1 - Symptom of Exposure Health/Environment Exposure can cause headache, nausea, confusion, drowsiness, dizziness and/or vomiting. Causes depression of central nervous system. Effects may be delayed. Lachrymator - causes tearing, blurred vision and pain in the eyes.
Potential health effects
May be irritating to eyes. Irritating to skin. (Skin corrosion/irritation, category 2) May be harmful if absorbed through the skin. (Acute toxicity, dermal, category 5) May be irritating to mucous membrane and upper respiratory system. (Specific target organ toxicity, single exposure; Respiratory tract irritation, category 3) Harmful if inhaled. (Acute toxicity, inhalation, category 4) Harmful if swallowed. (Acute toxicity, oral, category 4) 2.2.3 - Routes of Entry Inhalation, ingestion or skin contact. 2.2.4 - Carcinogenicity California Proposition 65 cancer hazard. California Proposition 65 Warning: This product contains a component (or components) that may cause cancer in a concentration greater than or equal to 0.1%. This product is or contains a component that is classified (ACGIH, IARC, NTP, OSHA) as a possible cancer hazard. (Carcinogenicity, category 1B)