Diphenylamine in Ethanol
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H225, H302, H312, H315, H320, H332, H335
Highly Flammable liquid and vapour
Harmful if swallowed
Harmful in contact with skin
Causes skin irritation
Causes eye irritation
Harmful if inhaled
May cause respiratory irritation
Do not handle until all safety precautions have been read and understood.
Keep container tightly closed.
Do not breathe dust/fume/gas/mist/vapors/spray.
Do not get in eyes, on skin, or on clothing.
Wash ... thoroughly after handling.
Wear protective gloves/protective clothing/eye protection/face protection.
[In case of inadequate ventilation] Wear respiratory protection.
Remove contact lenses, if present and easy to do. Continue rinsing.
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
Store in a closed container.
2.2 Label elements
3 * 2 HEALTH 2 0 3 FLAMMABILITY - continued P260 - Do not breathe vapor. P262 - Do not get in eyes, on skin or clothing. P264 - Wash thoroughly after handling. Do not take internally. Eye wash and safety equipment should be readily available. P280 - Protective gloves must be worn to prevent skin contact. P284 - Respiratory Protection: If workplace exposure limit(s) of product or any component is exceeded (see TLV/PEL), or a risk assessment shows air-purifying respirators are appropriate, use of a NIOSH/MSHA approved air supplied respirator is advised. Use a full-face respirator with multi-purpose combination (US) or type ABEK (EN14387) respirator cartridges in absence of proper environmental control. Always use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Engineering and/or administrative controls should be implemented to reduce exposure. P338 - Eye contact: Immediately flush with plenty of water. After initial flushing, remove and contact lenses and continue flushing for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. P340 - Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. P360 - Skin contact: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if symptoms occur. Wash clothing before reuse.
H225 - Highly Flammable (Flammable liquids, category 2) H302 - Harmful if swallowed. (Acute toxicity, oral, category 4) H312 - Harmful if absorbed through skin. (Acute toxicity, dermal, category 4) H315 - Irritating to skin. (Skin corrosion/irritation, category 2) H320 - Irritating to eyes. (Eye damage/irritation, category 2B) H332 - Harmful if inhaled. (Acute toxicity, inhalation, category 4) H335 - May be irritating to mucous membrane and upper respiratory system. (Specific target organ toxicity, single exposure; Respiratory tract irritation, category 3) Precautionary Codes: P202 - This product should only by used by persons trained in the safe handling of hazardous chemicals. P233 - Store in a tightly closed container. (P404) - continued
2.3 Other hazards
2.2.1 - Symptom of Exposure Health/Environment Highly Flammable (Flammable liquids, category 2) High concentrations or prolonged exposure causes headache, dizziness, nausea, irritation of eyes and respiratory tract, narcosis and eventually unconsciousness. High vapor concentrations may cause drowsiness. May cause eye damage. Causes depression of central nervous system.
Potential health effects
Irritating to eyes. (Eye damage/irritation, category 2B) Irritating to skin. (Skin corrosion/irritation, category 2) Harmful if absorbed through skin. (Acute toxicity, dermal, category 4) May be irritating to mucous membrane and upper respiratory system. (Specific target organ toxicity, single exposure; Respiratory tract irritation, category 3) Harmful if inhaled. (Acute toxicity, inhalation, category 4) Harmful if swallowed. (Acute toxicity, oral, category 4) 2.2.3 - Routes of Entry Inhalation, ingestion or skin contact. 2.2.4 - Carcinogenicity This product is or contains a component that is classified (ACGIH, IARC, NTP, OSHA) as probably not a cancer hazard.