Picric acid in Acetonitrile Methanol (50 50)
Methanol (50 50)
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H225, H301, H311, H315, H320, H332, H371
Highly Flammable liquid and vapour
Toxic if swallowed
Toxic in contact with skin
Causes skin irritation
Causes eye irritation
Harmful if inhaled
May cause damage to organs
Do not handle until all safety precautions have been read and understood.
Do not get in eyes, on skin, or on clothing.
Wash ... thoroughly after handling.
[In case of inadequate ventilation] Wear respiratory protection.
Remove contact lenses, if present and easy to do. Continue rinsing.
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
Store in a closed container.
2.2 Label elements
3 * 2 HEALTH 2 0 3 FLAMMABILITY 0 - continued P264 - Wash thoroughly after handling. Do not take internally. Eye wash and safety equipment should be readily available. P284 - Respiratory Protection: If workplace exposure limit(s) of product or any component is exceeded (see TLV/PEL), a NIOSH/MSHA approved air supplied respirator is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH/MSHA respirators (negative pressure type) under specified conditions (see your safety equipment supplier). Engineering and/or administrative controls should be implemented to reduce exposure. P338 - Eye contact: Immediately flush with plenty of water. After initial flushing, remove and contact lenses and continue flushing for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. P340 - Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. P360 - Skin contact: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if symptoms occur. Wash clothing before reuse. P404 - Store in a tightly closed container.
H225 - Highly Flammable (Flammable liquids, category 2) H301 - Toxic if swallowed. (Acute toxicity, oral, category 3) H311 - Toxic if absorbed through skin. (Acute toxicity, dermal, category 3) H315 - Irritating to skin. (Skin corrosion/irritation, category 2) H320 - Irritating to eyes. (Eye damage/irritation, category 2B) H332 - Harmful if inhaled. (Acute toxicity, inhalation, category 4) H371 - May cause heart damage. (Specific target organ toxicity, single exposure, category 1) Precautionary Codes: P202 - This product should only by used by persons trained in the safe handling of hazardous chemicals. P262 - Do not get in eyes, on skin or clothing. - continued
2.3 Other hazards
2.2.1 - Symptom of Exposure Health/Environment Highly Flammable (Flammable liquids, category 2) Effects may be delayed. May cause blood, central nervous system, kidneys, liver, lungs, and reproductive system damage. May cause heart damage. (Specific target organ toxicity, single exposure, category 1) Breathing high vapor concentrations may cause cyanide poisoning. Fetal development abnormalities and effects on embryo or fetus have been reported from prolonged exposure to methanol in laboratory tests involving pregnant rats. Overexposure may cause dizziness, nausea, muscle weakness, narcosis and respiratory failure.
Potential health effects
Irritating to eyes. (Eye damage/irritation, category 2B) Irritating to skin. (Skin corrosion/irritation, category 2) Toxic if absorbed through skin. (Acute toxicity, dermal, category 3) Irritating to mucous membrane and upper respiratory system. Harmful if inhaled. (Acute toxicity, inhalation, category 4) Toxic if swallowed. (Acute toxicity, oral, category 3) 2.2.3 - Routes of Entry Inhalation, ingestion or skin contact. 2.2.4 - Carcinogenicity This product is or contains a component that is classified (ACGIH, IARC, NTP, OSHA) as probably not a cancer hazard.