Tetrahydrothiophene in Methanol
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H225, H301, H311, H315, H320, H332, H336, H360, H370
Highly Flammable liquid and vapour
Toxic if swallowed
Toxic in contact with skin
Causes skin irritation
Causes eye irritation
Harmful if inhaled
May cause drowsiness or dizziness
May damage fertility or the unborn child
Causes damage to organs
Do not handle until all safety precautions have been read and understood.
Keep container tightly closed.
Do not get in eyes, on skin, or on clothing.
Wash ... thoroughly after handling.
Wear protective gloves/protective clothing/eye protection/face protection.
[In case of inadequate ventilation] Wear respiratory protection.
Do NOT induce vomiting.
Remove contact lenses, if present and easy to do. Continue rinsing.
Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
Store in a closed container.
2.2 Label elements
3 * 2 HEALTH 2 0 3 FLAMMABILITY - continued P202 - This product should only by used by persons trained in the safe handling of hazardous chemicals. P233 - Store in a tightly closed container. (P404) P262 - Do not get in eyes, on skin or clothing. P264 - Wash thoroughly after handling. Do not take internally. Eye wash and safety equipment should be readily available. P280 - Protective gloves must be worn to prevent skin contact. P284 - Respiratory Protection: If workplace exposure limit(s) of product or any component is exceeded (see TLV/PEL), or a risk assessment shows air-purifying respirators are appropriate, use of a NIOSH/MSHA approved air supplied respirator is advised. Use a full-face respirator with multi-purpose combination (US) or type ABEK (EN14387) respirator cartridges in absence of proper environmental control. Always use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Engineering and/or administrative controls should be implemented to reduce exposure. P331 - Ingestion: Do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. P338 - Eye contact: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. P360 - Skin contact: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if symptoms occur. Wash clothing before reuse.
H225 - Highly Flammable (Flammable liquids, category 2) H301 - Toxic if swallowed. (Acute toxicity, oral, category 3) H311 - Toxic if absorbed through skin. (Acute toxicity, dermal, category 3) H315 - Irritating to skin. (Skin corrosion/irritation, category 2) H320 - Irritating to eyes. (Eye damage/irritation, category 2B) H332 - Harmful if inhaled. (Acute toxicity, inhalation, category 4) H336 - Overexposure may cause dizziness, nausea, muscle weakness, narcosis and respiratory failure. H360 - California Proposition 65 Warning: This product contains a component (or components) that may cause birth defects or other reproductive harm in a quantity greater than or equal to 0.1%. H370 - Causes damage to organs. (Specific target organ toxicity, single exposure, category 1) Precautionary Codes: - continued
2.3 Other hazards
2.2.1 - Symptom of Exposure Health/Environment Highly Flammable (Flammable liquids, category 2) Causes damage to organs. (Specific target organ toxicity, single exposure, category 1) After ingestion or inhalation, initial symptoms may be only that of mild intoxication, but may become severe after 12 or 18 hours. POISON: May be fatal or cause blindness if swallowed. Overexposure may cause dizziness, nausea, muscle weakness, narcosis and respiratory failure.
Potential health effects
Irritating to eyes. (Eye damage/irritation, category 2B) Irritating to skin. (Skin corrosion/irritation, category 2) Toxic if absorbed through skin. (Acute toxicity, dermal, category 3) Irritating to mucous membrane and upper respiratory system. Harmful if inhaled. (Acute toxicity, inhalation, category 4) Toxic if swallowed. (Acute toxicity, oral, category 3) 2.2.3 - Routes of Entry Inhalation, ingestion or skin contact. 2.2.4 - Carcinogenicity California Proposition 65 Warning: This product contains a component (or components) that may cause birth defects or other reproductive harm in a quantity greater than or equal to 0.1%.