Tebbe reagent, 0.5M solution in toluene

Company name

Fisher Scientific

Signal word

Danger

2.1 Classification of the substance or mixture

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Flammable liquids Category 2 Skin Corrosion/irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Reproductive Toxicity Category 2 Specific target organ toxicity (single exposure) Category 3 Target Organs - Respiratory system, Central nervous system (CNS). Specific target organ toxicity - (repeated exposure) Category 2 Aspiration Toxicity Category 1

Signal word

Danger

Hazard statements

Highly flammable liquid and vapor May be fatal if swallowed and enters airways Causes severe skin burns and eye damage May cause respiratory irritation May cause drowsiness or dizziness Suspected of damaging fertility or the unborn child May cause damage to organs through prolonged or repeated exposure

Prevention

Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting/equipment Use only non-sparking tools Take precautionary measures against static discharge Keep cool

Response

IF exposed or concerned: Get medical attention/advice Get medical attention/advice if you feel unwell Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Skin IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse Immediately call a POISON CENTER or doctor/physician Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician Ingestion Do NOT induce vomiting IF SWALLOWED: Rinse mouth. DO NOT induce vomiting IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Fire In case of fire: Use CO2, dry chemical, or foam for extinction Explosion risk in case of fire Fight fire with normal precautions from a reasonable distance Evacuate area

Storage

Store locked up Store in a well-ventilated place. Keep container tightly closed

Disposal

Dispose of contents/container to an approved waste disposal plant

2.3 Other hazards

WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm.