4-Chloro-3-methylphenol for synthesis

Company name

Merck KGaA

E-mail address of the competent person responsible for the Safety Data Sheet

TechnicalService@merckgroup.com

Signal word

Danger

Hazard statements(CLP)

H302, H302+H312, H312, H314, H317, H318, H335, H400, H410, H412

Code

Statements

H302

Harmful if swallowed

H302+H312

Harmful if swallowed or in contact with skin

H312

Harmful in contact with skin

H314

Causes severe skin burns and eye damage

H317

May cause an allergic skin reaction

H318

Causes serious eye damage

H335

May cause respiratory irritation

H400

Very toxic to aquatic life

H410

Very toxic to aquatic life with long lasting effects

H412

Harmful to aquatic life with long lasting effects

Code

Statements

P260

Do not breathe dust/fume/gas/mist/vapors/spray.

P273

Avoid release to the environment.

P280

Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312

IF SWALLOWED: call a POISON CENTER/doctor/... IF you feel unwell.

P303+P361+P353

IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P305+P351+P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

CLP CLASSIFICATION

Acute toxicity, Oral (Category 4), H302 Acute toxicity, Dermal (Category 4), H312 Skin corrosion (Sub-category 1C), H314 Serious eye damage (Category 1), H318 Skin sensitization (Sub-category 1B), H317 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Short-term (acute) aquatic hazard (Category 1), H400 Long-term (chronic) aquatic hazard (Category 3), H412 For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

Labelling according Regulation (EC) No 1272/2008

Signal word

Danger Danger

Hazard statements

H302 + H312 Harmful if swallowed or in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects. Reduced Labeling (<= 125 ml) H317 May cause an allergic skin reaction. H314 Causes severe skin burns and eye damage.

Precautionary statements

P260 Do not breathe dusts or mists. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P260 Do not breathe dusts or mists. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental label elements

none none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.