(-)-Brucine for resolution of racemates for synthesis

company name

Merck KGaA

e-mail address of the competent person responsible for the Safety Data Sheet

TechnicalService@merckgroup.com

Signal Word

Danger

Hazard statements (CLP)

H300, H300+H330, H330, H412

Code

Statements

H300

Fatal if swallowed

H300+H330

Fatal if swallowed or if inhaled

H330

Fatal if inhaled

H412

Harmful to aquatic life with long lasting effects

Code

Statements

P260

Do not breathe dust/fume/gas/mist/vapors/spray.

P264

Wash ... thoroughly after handling.

P270

Do not eat, drink or smoke when using this product.

P271

Use only outdoors or in a well-ventilated area.

P273

Avoid release to the environment.

CLP CLASSIFICATION

Acute toxicity, Oral (Category 1), H300 Acute toxicity, Inhalation (Category 2), H330 Long-term (chronic) aquatic hazard (Category 3), H412 For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

Labelling according Regulation (EC) No 1272/2008

Signal word

Danger Danger

Hazard statements

H300 + H330 Fatal if swallowed or if inhaled. H412 Harmful to aquatic life with long lasting effects. Reduced Labeling (<= 125 ml) H412 Harmful to aquatic life with long lasting effects. H300 + H330 Fatal if swallowed or if inhaled.

Precautionary statements

P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.

Supplemental label elements

none none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.