Morpholine for synthesis

Company name

Sigma-Aldrich Chemie GmbH

E-mail address of the competent person responsible for the Safety Data Sheet

technischerservice@merckgroup.com

Signal word

Danger

Hazard statements (CLP)

H226, H302, H311, H311+H331, H314, H318, H331, H361fd

Code

Statements

H226

Flammable liquid and vapour

H302

Harmful if swallowed

H311

Toxic in contact with skin

H311+H331

Toxic in contact with skin or if inhaled.

H314

Causes severe skin burns and eye damage

H318

Causes serious eye damage

H331

Toxic if inhaled

H361fd

Suspected of damaging fertility; Suspected of damaging the unborn child

Code

Statements

P210

Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P280

Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312

IF SWALLOWED: call a POISON CENTER/doctor/... IF you feel unwell.

P303+P361+P353

IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P305+P351+P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

2.1 Classification of the substance or mixture

Classification

2.2 Label elements

Labelling

Signal word

Danger Danger

Hazard statements

H226 Flammable liquid and vapor. H302 Harmful if swallowed. H311 + H331 Toxic in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. H361fd Suspected of damaging fertility. Suspected of damaging the unborn child. Reduced Labeling (<= 125 ml) H314 Causes severe skin burns and eye damage. H361fd Suspected of damaging fertility. Suspected of damaging the unborn child. H311 + H331 Toxic in contact with skin or if inhaled.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental label elements

none none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.