Oxalyl chloride solution

Company name

Sigma-Aldrich Chemie GmbH

E-mail address of the competent person responsible for the Safety Data Sheet

technischerservice@merckgroup.com

Signal word

Danger

Hazard statements (CLP)

H260, H302, H314, H318, H331, H336, H351

Code

Statements

H260

In contact with water releases flammable gases which may ignite spontaneously

H302

Harmful if swallowed

H314

Causes severe skin burns and eye damage

H318

Causes serious eye damage

H331

Toxic if inhaled

H336

May cause drowsiness or dizziness

H351

Suspected of causing cancer

Code

Statements

P231+P232

Handle under inert gas/... Protect from moisture.

P280

Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312

IF SWALLOWED: call a POISON CENTER/doctor/... IF you feel unwell.

P303+P361+P353

IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P305+P351+P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

Code

Statements

EUH014

Reacts violently with water

EUH029

Contact with water liberates toxic gas

EUH071

Corrosive to the respiratory tract

2.1 Classification of the substance or mixture

Classification

2.2 Label elements

Labelling

Signal word

Danger Danger

Hazard statements

H260 In contact with water releases flammable gases which may ignite spontaneously. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H331 Toxic if inhaled. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H331 Toxic if inhaled. H351 Suspected of causing cancer. H314 Causes severe skin burns and eye damage.

Precautionary statements

P231 + P232 Handle and store contents under inert gas. Protect from moisture. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental label elements

EUH014 Reacts violently with water. EUH029 Contact with water liberates toxic gas. EUH071 Corrosive to the respiratory tract. Reduced Labeling (<= 125 ml) EUH014 Reacts violently with water. EUH029 Contact with water liberates toxic gas. EUH071 Corrosive to the respiratory tract.

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.