Hydrazine hydrate

Company name

Sigma-Aldrich

Signal word

Danger

Hazard statements (CLP)

H301, H301+H311+H331, H311, H314, H317, H318, H331, H350, H400, H410

Code

Statements

H301

Toxic if swallowed

H301+H311+H331

Toxic if swallowed, in contact with skin or if inhaled

H311

Toxic in contact with skin

H314

Causes severe skin burns and eye damage

H317

May cause an allergic skin reaction

H318

Causes serious eye damage

H331

Toxic if inhaled

H350

May cause cancer

H400

Very toxic to aquatic life

H410

Very toxic to aquatic life with long lasting effects

Code

Statements

P201

Obtain special instructions before use.

P202

Do not handle until all safety precautions have been read and understood.

P261

Avoid breathing dust/fume/gas/mist/vapors/spray.

P264

Wash ... thoroughly after handling.

P270

Do not eat, drink or smoke when using this product.

P271

Use only outdoors or in a well-ventilated area.

P272

Contaminated work clothing should not be allowed out of the workplace.

P273

Avoid release to the environment.

P280

Wear protective gloves/protective clothing/eye protection/face protection.

P281

Use personal protective equipment as required.

P301+P330+P331

IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353

IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P308+P313

IF exposed or concerned: Get medical advice/attention.

P333+P313

IF SKIN irritation or rash occurs: Get medical advice/attention.

P363

Wash contaminated clothing before reuse.

P391

Collect spillage.

P403+P233

Store in a well-ventilated place. Keep container tightly closed.

P405

Store locked up.

P501

Dispose of contents/container to ...

OSHA HCS Classification

Acute toxicity, Oral (Category 3), H301 Acute toxicity, Inhalation (Category 3), H331 Acute toxicity, Dermal (Category 3), H311 Skin corrosion (Category 1B), H314 Serious eye damage (Category 1), H318 Skin sensitisation (Category 1), H317 Carcinogenicity (Category 1B), H350 Acute aquatic toxicity (Category 1), H400 Chronic aquatic toxicity (Category 1), H410 For the full text of the H-Statements mentioned in this Section, see Section 16.

Signal word

Danger

Hazard statements

H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H350 May cause cancer. H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P281 Use personal protective equipment as required. P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P363 Wash contaminated clothing before reuse. P391 Collect spillage. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Other hazards

none