1 M Biphenyl in THF, a precursor solution to

Company name

Sigma-Aldrich Inc

Signal word

Danger

Hazard statements (CLP)

H225, H302, H315, H319, H335, H336, H351, H411

Code

Statements

H225

Highly Flammable liquid and vapour

H302

Harmful if swallowed

H315

Causes skin irritation

H319

Causes serious eye irritation

H335

May cause respiratory irritation

H336

May cause drowsiness or dizziness

H351

Suspected of causing cancer

H411

Toxic to aquatic life with long lasting effects

Code

Statements

P210

Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P273

Avoid release to the environment.

P301+P312

IF SWALLOWED: call a POISON CENTER/doctor/... IF you feel unwell.

P303+P361+P353

IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P305+P351+P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P308+P313

IF exposed or concerned: Get medical advice/attention.

Code

Statements

EUH018

In use, may form flammable/explosive vapour-air mixture

EUH019

May form explosive peroxides

2.1 Classification of the substance or mixture

Classification

2.2 Label elements

Labelling

Signal word

Danger Danger

Hazard statements

H225 Highly flammable liquid and vapor. H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H411 Toxic to aquatic life with long lasting effects. H351 Suspected of causing cancer.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P308 + P313 IF exposed or concerned: Get medical advice/ attention.

Supplemental label elements

EUH018 In use may form flammable/explosive vapor-air mixture. EUH019 May form explosive peroxides. Reduced Labeling (<= 125 ml) EUH018 In use may form flammable/explosive vapor-air mixture. EUH019 May form explosive peroxides.

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.