Chloroform-d

Company name

Sigma-Aldrich Inc

Signal word

Danger

Hazard statements (CLP)

H302, H315, H319, H331, H336, H351, H361, H372, H402

Code

Statements

H302

Harmful if swallowed

H315

Causes skin irritation

H319

Causes serious eye irritation

H331

Toxic if inhaled

H336

May cause drowsiness or dizziness

H351

Suspected of causing cancer

H361

Suspected of damaging fertility or the unborn child

H372

Causes damage to organs through prolonged or repeated exposure

H402

Harmful to aquatic life

Code

Statements

P201

Obtain special instructions before use.

P202

Do not handle until all safety precautions have been read and understood.

P260

Do not breathe dust/fume/gas/mist/vapors/spray.

P264

Wash ... thoroughly after handling.

P270

Do not eat, drink or smoke when using this product.

P271

Use only outdoors or in a well-ventilated area.

P273

Avoid release to the environment.

P280

Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352

IF ON SKIN: wash with plenty of water.

P305+P351+P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P308+P313

IF exposed or concerned: Get medical advice/attention.

P332+P313

IF SKIN irritation occurs: Get medical advice/attention.

P337+P313

IF eye irritation persists: Get medical advice/attention.

P362

Take off contaminated clothing.

P403+P233

Store in a well-ventilated place. Keep container tightly closed.

P405

Store locked up.

P501

Dispose of contents/container to ...

OSHA HCS Classification

Acute toxicity, Oral (Category 4), H302 Acute toxicity, Inhalation (Category 3), H331 Skin irritation (Category 2), H315 Eye irritation (Category 2A), H319 Carcinogenicity (Category 2), H351 Reproductive toxicity (Category 2), H361 Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336 Specific target organ toxicity - repeated exposure, Oral (Category 1), Liver, Kidney, H372 Short-term (acute) aquatic hazard (Category 3), H402 For the full text of the H-Statements mentioned in this Section, see Section 16.

Signal word

Danger

Hazard statements

H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H331 Toxic if inhaled. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H361 Suspected of damaging fertility or the unborn child. H372 Causes damage to organs (Liver, Kidney) through prolonged or repeated exposure if swallowed. H402 Harmful to aquatic life.

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Other hazards

none