Crotonaldehyde, predominantly trans

Company name

Sigma-Aldrich Inc

Signal word

Danger

Hazard statements (CLP)

H225, H301, H301+H311, H311, H315, H318, H330, H335, H341, H351, H373, H400

Code

Statements

H225

Highly Flammable liquid and vapour

H301

Toxic if swallowed

H301+H311

Toxic if swallowed or in contact with skin

H311

Toxic in contact with skin

H315

Causes skin irritation

H318

Causes serious eye damage

H330

Fatal if inhaled

H335

May cause respiratory irritation

H341

Suspected of causing genetic defects

H351

Suspected of causing cancer

H373

Causes damage to organs through prolonged or repeated exposure

H400

Very toxic to aquatic life

Code

Statements

P201

Obtain special instructions before use.

P202

Do not handle until all safety precautions have been read and understood.

P210

Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P233

Keep container tightly closed.

P240

Ground/bond container and receiving equipment.

P241

Use explosion-proof [electrical/ventilating/lighting/.../] equipment.

P242

Use only non-sparking tools.

P243

Take precautionary measures against static discharge.

P260

Do not breathe dust/fume/gas/mist/vapors/spray.

P264

Wash ... thoroughly after handling.

P270

Do not eat, drink or smoke when using this product.

P271

Use only outdoors or in a well-ventilated area.

P273

Avoid release to the environment.

P280

Wear protective gloves/protective clothing/eye protection/face protection.

P284

[In case of inadequate ventilation] Wear respiratory protection.

P303+P361+P353

IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P305+P351+P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P308+P313

IF exposed or concerned: Get medical advice/attention.

P310

Immediately call a POISON CENTER or doctor/physician.

P332+P313

IF SKIN irritation occurs: Get medical advice/attention.

P362

Take off contaminated clothing.

P370+P378

In case of fire: Use ... to extinguish.

P391

Collect spillage.

P403+P233

Store in a well-ventilated place. Keep container tightly closed.

P403+P235

Store in a well-ventilated place. Keep cool.

P405

Store locked up.

P501

Dispose of contents/container to ...

OSHA HCS Classification

Flammable liquids (Category 2), H225 Acute toxicity, Oral (Category 3), H301 Acute toxicity, Inhalation (Category 1), H330 Acute toxicity, Dermal (Category 3), H311 Skin irritation (Category 2), H315 Serious eye damage (Category 1), H318 Germ cell mutagenicity (Category 2), H341 Carcinogenicity (Category 2), H351 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Specific target organ toxicity - repeated exposure (Category 2), H373 Short-term (acute) aquatic hazard (Category 1), H400 For the full text of the H-Statements mentioned in this Section, see Section 16.

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapor. H301 + H311 Toxic if swallowed or in contact with skin. H315 Causes skin irritation. H318 Causes serious eye damage. H330 Fatal if inhaled. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life.

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe mist or vapors. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 Wear respiratory protection. P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P391 Collect spillage. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Other hazards

Lachrymator.