Diisopropylzinc solution

Company name

Sigma-Aldrich Inc

Signal word

Danger

Hazard statements(CLP)

H225, H250, H261, H304, H314, H318, H336, H361, H373, H401, H412

Code

Statements

H225

Highly Flammable liquid and vapour

H250

Catches fire spontaneously if exposed to air

H261

In contact with water releases flammable gas

H304

May be fatal if swallowed and enters airways

H314

Causes severe skin burns and eye damage

H318

Causes serious eye damage

H336

May cause drowsiness or dizziness

H361

Suspected of damaging fertility or the unborn child

H373

Causes damage to organs through prolonged or repeated exposure

H401

Toxic to aquatic life

H412

Harmful to aquatic life with long lasting effects

Code

Statements

P201

Obtain special instructions before use.

P202

Do not handle until all safety precautions have been read and understood.

P210

Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P222

Do not allow contact with air.

P223

Do not allow contact with water.

P231+P232

Handle under inert gas/... Protect from moisture.

P233

Keep container tightly closed.

P240

Ground/bond container and receiving equipment.

P241

Use explosion-proof [electrical/ventilating/lighting/.../] equipment.

P242

Use only non-sparking tools.

P243

Take precautionary measures against static discharge.

P260

Do not breathe dust/fume/gas/mist/vapors/spray.

P264

Wash ... thoroughly after handling.

P271

Use only outdoors or in a well-ventilated area.

P273

Avoid release to the environment.

P280

Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310

IF SWALLOWED: Immediately call a POISON CENTER/doctor/...

P301+P330+P331

IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P302+P334

IF ON SKIN: Immerse in cool water [or wrap in wet bandages].

P303+P361+P353

IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P305+P351+P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P308+P313

IF exposed or concerned: Get medical advice/attention.

P310

Immediately call a POISON CENTER or doctor/physician.

P335+P334

Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.

P363

Wash contaminated clothing before reuse.

P370+P378

In case of fire: Use ... to extinguish.

P402+P404

Store in a dry place. Store in a closed container.

P403+P233

Store in a well-ventilated place. Keep container tightly closed.

P403+P235

Store in a well-ventilated place. Keep cool.

P405

Store locked up.

P422

Store contents under ...

P501

Dispose of contents/container to ...

Aspiration hazard

Category 1), H304 Short-term (acute) aquatic hazard (Category 2), H401 Long-term (chronic) aquatic hazard (Category 3), H412 For the full text of the H-Statements mentioned in this Section, see Section 16.

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapor. H250 Catches fire spontaneously if exposed to air. H261 In contact with water releases flammable gas. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H336 May cause drowsiness or dizziness. H361 Suspected of damaging fertility or the unborn child. H373 May cause damage to organs (Central nervous system) through prolonged or repeated exposure. H401 Toxic to aquatic life. H412 Harmful to aquatic life with long lasting effects.

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P222 Do not allow contact with air. P223 Do not allow contact with water. P231 + P232 Handle under inert gas. Protect from moisture. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302 + P334 IF ON SKIN: Immerse in cool water/ wrap in wet bandages. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P335 + P334 Brush off loose particles from skin. Immerse in cool water/ wrap in wet bandages. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P402 + P404 Store in a dry place. Store in a closed container. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P422 Store contents under inert gas. P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Other hazards

Reacts violently with water.