Hydrazine hydrate

Company name

Sigma-Aldrich Inc

Signal word

Danger

Hazard statements (CLP)

H226, H301, H301+H311+H331, H311, H314, H317, H318, H331, H350, H400, H410

Code

Statements

H226

Flammable liquid and vapour

H301

Toxic if swallowed

H301+H311+H331

Toxic if swallowed, in contact with skin or if inhaled

H311

Toxic in contact with skin

H314

Causes severe skin burns and eye damage

H317

May cause an allergic skin reaction

H318

Causes serious eye damage

H331

Toxic if inhaled

H350

May cause cancer

H400

Very toxic to aquatic life

H410

Very toxic to aquatic life with long lasting effects

Code

Statements

P201

Obtain special instructions before use.

P202

Do not handle until all safety precautions have been read and understood.

P210

Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P233

Keep container tightly closed.

P240

Ground/bond container and receiving equipment.

P241

Use explosion-proof [electrical/ventilating/lighting/.../] equipment.

P242

Use only non-sparking tools.

P243

Take precautionary measures against static discharge.

P261

Avoid breathing dust/fume/gas/mist/vapors/spray.

P264

Wash ... thoroughly after handling.

P270

Do not eat, drink or smoke when using this product.

P271

Use only outdoors or in a well-ventilated area.

P272

Contaminated work clothing should not be allowed out of the workplace.

P273

Avoid release to the environment.

P280

Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331

IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353

IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P305+P351+P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P308+P313

IF exposed or concerned: Get medical advice/attention.

P310

Immediately call a POISON CENTER or doctor/physician.

P333+P313

IF SKIN irritation or rash occurs: Get medical advice/attention.

P362

Take off contaminated clothing.

P370+P378

In case of fire: Use ... to extinguish.

P391

Collect spillage.

P403+P233

Store in a well-ventilated place. Keep container tightly closed.

P403+P235

Store in a well-ventilated place. Keep cool.

P405

Store locked up.

P501

Dispose of contents/container to ...

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapor. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H350 May cause cancer. H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing mist or vapors. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing must not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P391 Collect spillage. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Other hazards

none