Methyl Isobutyl Ketone, United States

Company name

Sigma-Aldrich Inc

Signal word

Danger

Hazard statements (CLP)

H225, H319, H332, H336, H351

Code

Statements

H225

Highly Flammable liquid and vapour

H319

Causes serious eye irritation

H332

Harmful if inhaled

H336

May cause drowsiness or dizziness

H351

Suspected of causing cancer

Code

Statements

P201

Obtain special instructions before use.

P202

Do not handle until all safety precautions have been read and understood.

P210

Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P233

Keep container tightly closed.

P240

Ground/bond container and receiving equipment.

P241

Use explosion-proof [electrical/ventilating/lighting/.../] equipment.

P242

Use only non-sparking tools.

P243

Take precautionary measures against static discharge.

P261

Avoid breathing dust/fume/gas/mist/vapors/spray.

P264

Wash ... thoroughly after handling.

P271

Use only outdoors or in a well-ventilated area.

P280

Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353

IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P305+P351+P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P308+P313

IF exposed or concerned: Get medical advice/attention.

P337+P313

IF eye irritation persists: Get medical advice/attention.

P370+P378

In case of fire: Use ... to extinguish.

P403+P233

Store in a well-ventilated place. Keep container tightly closed.

P403+P235

Store in a well-ventilated place. Keep cool.

P405

Store locked up.

P501

Dispose of contents/container to ...

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapor. H319 Causes serious eye irritation. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer if inhaled.

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing mist or vapors. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Other hazards

Repeated exposure may cause skin dryness or cracking.