Phenylmagnesium bromide solution

Company name

Sigma-Aldrich Inc

Signal word

Danger

Hazard statements (CLP)

H225, H314, H318, H336

Code

Statements

H225

Highly Flammable liquid and vapour

H314

Causes severe skin burns and eye damage

H318

Causes serious eye damage

H336

May cause drowsiness or dizziness

Code

Statements

P210

Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P233

Keep container tightly closed.

P240

Ground/bond container and receiving equipment.

P241

Use explosion-proof [electrical/ventilating/lighting/.../] equipment.

P242

Use only non-sparking tools.

P243

Take precautionary measures against static discharge.

P261

Avoid breathing dust/fume/gas/mist/vapors/spray.

P264

Wash ... thoroughly after handling.

P271

Use only outdoors or in a well-ventilated area.

P280

Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331

IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353

IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P305+P351+P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P310

Immediately call a POISON CENTER or doctor/physician.

P363

Wash contaminated clothing before reuse.

P370+P378

In case of fire: Use ... to extinguish.

P403+P233

Store in a well-ventilated place. Keep container tightly closed.

P403+P235

Store in a well-ventilated place. Keep cool.

P405

Store locked up.

P501

Dispose of contents/container to ...

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapor. H314 Causes severe skin burns and eye damage. H336 May cause drowsiness or dizziness.

Precautionary statements

P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Other hazards

Reacts violently with water. May form explosive peroxides.