EC/CAS
200-838-9/75-09-2
Name of the chemical
Methylene chloride
Concentration
>=70-<90
Version
6.7
Revision date
2023-04-14
Product name
Titanium(IV) chloride solution
REACH No
This
Emergency telephone
800-424-9300 CHEMTREC (USA) +1-703- 527-3887 CHEMTREC (International) 24
Icons in SDS
Company name
Sigma-Aldrich Inc
Signal word
Danger
Hazard statements (CLP)
H314, H318, H331, H336, H351
Code
Statements
H314
Causes severe skin burns and eye damage
H318
Causes serious eye damage
H331
Toxic if inhaled
H336
May cause drowsiness or dizziness
H351
Suspected of causing cancer
Code
Statements
P201
Obtain special instructions before use.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353
IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].
P305+P351+P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.
P308+P313
IF exposed or concerned: Get medical advice/attention.
P310
Immediately call a POISON CENTER or doctor/physician.
Code
Statements
EUH014
Reacts violently with water
2.1 Classification of the substance or mixture
Classification
2.2 Label elements
Labelling
Signal word
Danger Danger
Hazard statements
H314 Causes severe skin burns and eye damage. H331 Toxic if inhaled. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H331 Toxic if inhaled. H314 Causes severe skin burns and eye damage. H351 Suspected of causing cancer.
Precautionary statements
P201 Obtain special instructions before use. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P201 Obtain special instructions before use. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes. P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention.
Supplemental label elements
EUH014 Reacts violently with water. Reduced Labeling (<= 125 ml) EUH014 Reacts violently with water.
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Lachrymator.