EC/CAS
200-659-6/67-56-1
Name of the chemical
Methanol
Concentration
>=90-< 100% 603-001-
Version
8.7
Revision date
2023-02-07
Product name
Toluene solution
Emergency telephone
800-424-9300 CHEMTREC (USA) +1-703- 527-3887 CHEMTREC (International) 24
Icons in SDS
Company name
Sigma-Aldrich Inc
Signal word
Danger
Hazard statements (CLP)
H225, H301, H301+H311+H331, H311, H331, H370
Code
Statements
H225
Highly Flammable liquid and vapour
H301
Toxic if swallowed
H301+H311+H331
Toxic if swallowed, in contact with skin or if inhaled
H311
Toxic in contact with skin
H331
Toxic if inhaled
H370
Causes damage to organs
Code
Statements
P210
Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.
P233
Keep container tightly closed.
P240
Ground/bond container and receiving equipment.
P241
Use explosion-proof [electrical/ventilating/lighting/.../] equipment.
P242
Use only non-sparking tools.
P243
Take precautionary measures against static discharge.
P260
Do not breathe dust/fume/gas/mist/vapors/spray.
P264
Wash ... thoroughly after handling.
P270
Do not eat, drink or smoke when using this product.
P271
Use only outdoors or in a well-ventilated area.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353
IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].
P307+P311
IF exposed: call a POISON CENTER or doctor/physician.
P362
Take off contaminated clothing.
P370+P378
In case of fire: Use ... to extinguish.
P403+P233
Store in a well-ventilated place. Keep container tightly closed.
P403+P235
Store in a well-ventilated place. Keep cool.
P405
Store locked up.
P501
Dispose of contents/container to ...
Signal word
Danger
Hazard statements
H225 Highly flammable liquid and vapor. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H370 Causes damage to organs (Eyes).
Precautionary statements
P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ eye protection/ face protection. P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P307 + P311 IF exposed: Call a POISON CENTER or doctor/ physician. P362 Take off contaminated clothing and wash before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/ container to an approved waste disposal plant.
2.3 Other hazards
none