2,4-Difluorobenzylzinc bromide, 0.5M in THF

Company name

ThermoFisher Scientific Australia Pty Ltd

E-mail address of the competent person responsible for the Safety Data Sheet

ANZinfo@thermofisher.com

Signal word

Danger

Hazard statements (CLP)

H225, H261, H302, H314, H335, H336, H351

Code

Statements

H225

Highly Flammable liquid and vapour

H261

In contact with water releases flammable gas

H302

Harmful if swallowed

H314

Causes severe skin burns and eye damage

H335

May cause respiratory irritation

H336

May cause drowsiness or dizziness

H351

Suspected of causing cancer

Code

Statements

P201

Obtain special instructions before use.

P202

Do not handle until all safety precautions have been read and understood.

P210

Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.

P223

Do not allow contact with water.

P231+P232

Handle under inert gas/... Protect from moisture.

P233

Keep container tightly closed.

P240

Ground/bond container and receiving equipment.

P242

Use only non-sparking tools.

P243

Take precautionary measures against static discharge.

P260

Do not breathe dust/fume/gas/mist/vapors/spray.

P264

Wash ... thoroughly after handling.

P270

Do not eat, drink or smoke when using this product.

P271

Use only outdoors or in a well-ventilated area.

P280

Wear protective gloves/protective clothing/eye protection/face protection.

P302+P335+P334

Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages].

P303+P361+P353

IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].

P304+P340

IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P305+P351+P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P310

Immediately call a POISON CENTER or doctor/physician.

P330

Rinse mouth.

P331

Do NOT induce vomiting.

P363

Wash contaminated clothing before reuse.

P370+P378

In case of fire: Use ... to extinguish.

P402+P404

Store in a dry place. Store in a closed container.

P501

Dispose of contents/container to ...

SECTION 2: Hazards identification

Classification under Safe Work Australia Classified as hazardous according to criteria of Safe Work Australia

Physical hazards

Flammable liquids Category 2 Substances/mixtures which, in contact with water, emit flammable gases Category 2

Health hazards

Acute Oral Toxicity Category 4 Skin Corrosion/Irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Carcinogenicity Category 2 Specific target organ toxicity - (single exposure) Category 3 Corrosion

Environmental hazards

No hazards identified

2.2 Label elements

Flame Exclamation Mark

Signal word

Danger

Hazard statements

H225 - Highly flammable liquid and vapor H261 - In contact with water releases flammable gases H302 - Harmful if swallowed H314 - Causes severe skin burns and eye damage H335 - May cause respiratory irritation H336 - May cause drowsiness or dizziness H351 - Suspected of causing cancer AUH019 - May form explosive peroxides

Precautionary statements

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P223 - Do not allow contact with water P231 + P232 - Handle and store contents under inert gas. Protect from moisture P233 - Keep container tightly closed P240 - Ground and bond container and receiving equipment P242 - Use non-sparking tools P243 - Take action to prevent static discharges P260 - Do not breathe dust/fume/gas/mist/vapors/spray P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P330 - Rinse mouth P331 - Do NOT induce vomiting P363 - Wash contaminated clothing before reuse P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish P302 + P335 + P334 - IF ON SKIN: Brush off loose particles from skin. Immerse in cool water P402 + P404 - Store in a dry place. Store in a closed container P501 - Dispose of contents/ container to an approved waste disposal plant

Further information

Toxic to terrestrial vertebrates